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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 7339-7346 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Scaling of electromigration test results for near-bamboo interconnects from accelerated test conditions to service conditions requires an understanding of the microstructural characteristics of the interconnects. An analytic model has been developed that allows prediction of the average polygranular cluster lengths and the number of clusters in a line, given the linewidth, the line length, and the characteristics of the grain size distribution of the original film. Grain-structure characteristics have also been measured for lines patterned from computer-generated thin-film microstructures. The large-cluster-length tail of the polygranular cluster-length distribution is well fit by an exponential distribution function, which can be accurately predicted using our new analytic model. Polycrystalline clusters shorter than a critical length Lcr cannot fail due to electromigration-induced grain-boundary diffusion alone, so that when all clusters in a line are shorter than Lcr, there is a transition in failure mechanisms. The model can be used to calculate the number of clusters longer than Lcr as a function of the line and grain-structure characteristics, as well as a function of the current density. The current-density dependence of the median time to failure due to polygranular failure mechanisms in near-bamboo lines, as well as the transition current density at which the transition in failure mechanisms occurs are predicted. This transition current density depends on the linewidth and the line length, as well as the grain size and grain size distribution of the film from which the line was patterned. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 6062-6072 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Passivated and unpassivated Al single-crystal lines with (110), (133), and (111) planes parallel to the substrate have been fabricated and electromigration tests have been performed to study transgranular failure mechanisms. Both erosion voids and slitlike voids with {111} facets were observed in single-crystal lines. The slitlike voids lie along the in-plane direction, which leads to minimum-surface-area voids among the crystallographically possible directions for the {111}-faceted voids. Voids that nucleate in the lines appear to be mobile and can move toward the cathode end and sometimes accumulate in the cathode pad. (110)-textured lines fail due to erosion voids, slitlike voids, and pad voids, with roughly equal probability. However, (111)- and (133)-textured lines failed predominantly due to pad voids. In both passivated and unpassivated single-crystal lines, the median time to failure, t50, is texture dependent, with t50(111)〉t50(133)〉t50(110), and with t50(111)≥10×t50(110). The activation energy for failure for (110) single-crystal lines is about 1 eV, suggesting that Al/oxide interface diffusion may be the dominant mechanism in these lines, and by inference, in bamboo grains in lines with near-bamboo or fully bamboo microstructures. The current density exponent for failure times of single-crystal lines is about 2.5, which is close to that of polycrystalline lines. Based on the results of this study, coupled with results from an earlier model for calculation of lifetimes due to polygranular failure mechanisms, an improved scaling methodology for projection of lifetimes from test conditions to service conditions for near-bamboo interconnects is proposed. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The texture of electroplated Cu lines of 0.375, 0.5 and 1.5 μm widths with Ta and TiN barrier layers was analyzed using x-ray pole figure and electron backscatter diffraction (EBSD) techniques. Both techniques indicate a strong (111) fiber texture relative to the bottom surface of the trench for samples with a Ta barrier layer and a 400 °C, 30 min, postelectroplating anneal. Samples with a TiN barrier and no anneal exhibit a weak (111) texture. For both barrier layers the quality of the texture, as measured by (111) peak intensity, fraction of randomly oriented grains and (111) peak width, degrades with decreasing linewidth. EBSD data also indicate (111) texture relative to the sidewalls of the trench in samples with a Ta barrier and postelectroplating anneal. Electromigration tests at 300 °C of 0.36 μm damascene Cu lines with the same process conditions show that samples with very weak (111) texture have median time to failures that exceed those of the strongly textured Cu lines. These results indicate that diffusion at interfaces, such as the Cu/barrier and Cu/overlayer interfaces, along with diffusion along an electroplating seam play more dominant roles in electromigration failure in damascene-fabricated lines than diffusion along grain boundaries within the interconnect. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Solid state phenomena Vol. 124-126 (June 2007), p. 9-12 
    ISSN: 1662-9779
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Physics
    Notes: In-situ observation by scanning electron microscope of the microstructure evolution nearthe cathode depletion region and the quantitative analysis on the number of hillock phases in theeutectic SnPb edge drift structure made it clear that the dominant migrating element and dominanthillock phase were Sn and Pb, respectively, under 50 oC while both dominant migrating element anddominant hillock phase were Pb above 100 oC. Such temperature-dependence of the dominant hillockphases in the eutectic SnPb solder can be understood by considering the atomic size factors of themetallic solid solutions
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 467-470 (Oct. 2004), p. 917-922 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 475-479 (Jan. 2005), p. 3641-3646 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The reaction induced phase separation aimed for the distribution of nano-structured particles has been investigated by transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) in ternary Ti-Si-N film via N+ implantation. The fabrication of Ti-20at%Si film has made on Si substrates by ion beam sputtering (IBS), and then N+ implantation with 50 keV has been conducted on these films. The selected area electron diffraction (SAED) from as-deposited film shows amorphous Ti-Si. As-deposited Ti-Si film exhibited high stability even for the heat treatment at 773K for 3600s. N+ implantation induced the direct formation of nano crystalline of fcc-TiNx within the Ti-Si film. The XPS depth profiling and chemical shift suggest that the preferential nitriding of Ti accompanied with the segregation of SiNx occurred during N-implantation
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 539-543 (Mar. 2007), p. 3520-3524 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Hillocks were observed in various thick Al films after annealing for a long time and theirdensity and diameter were measured using an image analysis program. The hillock density decreasedwhile the diameter increased with increasing film thickness. The total hillock volume per unit area ofthe film is linearly proportional to the film thickness and annealing temperature. Based on the resultsof our investigation, the effect of the film thickness, grain size and annealing temperature on hillockformation is discussed, and an equation that can be used to predict the hillock density and averagehillock diameter is suggested
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 558-559 (Oct. 2007), p. 1453-1457 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The distribution of the precipitates on the grain boundaries in Fe-3%Si steel duringsecondary recrystallization annealing were studied using high-angle annular dark filed (HAADF)scanning transmission electron microscopy (STEM). Because HAADF image can show both grainboundaries and precipitates clearly, the change of precipitate distribution on grain boundaries can bequantitatively analyzed. It was observed that the total area of the precipitates on grain boundariesincreased in the order of non-annealed, 600°C, and 900°C sample and the total area of precipitates ongrain boundaries in the 1000 °C sample was much lower than that in the 900 °C sample. Thecompositions of the precipitates were also analyzed using X-ray energy-dispersive spectrometer(XEDS). The most precipitates were multi-phase ones, mainly composed of AlN and MnS. Ouranalysis results suggest that such a precipitate behavior is responsible for the abnormal grain growthof Fe-3%Si steel occurring under the temperature above 900 °C
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 558-559 (Oct. 2007), p. 1243-1248 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Use of silver (Ag) nanoparticle suspension for various applications such as ink-jetprinting of electronic circuits has been of prime interest. We observed the microstructure evolutionof the inkjet-printed Ag thin films on Si substrates under various annealing conditions using thefield-emission scanning electron microscopy (FE-SEM). Abnormal grain growth characteristicswere identified when annealed at about 240 oC under ambient air. Growth characteristics of poreswere found to be in accordance with that of grains. Competition between grain and pore growth isattributed to small grain sizes, low packing density and high porosity, which are characteristic ofinkjet-printed Ag films as dried
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 408-412 (Aug. 2002), p. 529-534 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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