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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 28 (1998), S. 36-43 
    ISSN: 1432-0789
    Keywords: Key words Nitrous oxide ; Forage crops ; Spring barley ; Nitrogen fertiliser ; Thawing and freezing cycles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  N2O emission rates from a sandy loam soil were measured in a field experiment with 2 years of perennial forage crops (ryegrass, ryegrass-red clover, red clover) and 1 year of spring barley cultivation. Spring barley was sown after the incorporation of the forage crop residues. All spring barley plots received 40 kg N ha–1 N fertiliser. Ryegrass, ryegrass-red clover and red clover plots were fertilised with 350 kg N ha–1, 175 kg N ha–1 and 0 kg N ha–1, respectively. From June 1994 to February 1997, N2O fluxes were continuously estimated using very large, closed soil cover boxes (5.76 m2). In order to compare the growing crops, the 33 months of investigation were separated into three vegetation periods (March–September) and three winter periods (October–February). All agronomic treatments (fertilisation, harvest and tillage) were carried out during the vegetation period. Large temporal changes were found in the N2O emission rates. The data were approximately log-normally distributed. Forty-seven percent of the annual N2O losses were observed to occur during winter, and mainly resulted from N2O production during daily thawing and freezing cycles. No relationship was found between the N2O emissions during the winter and the vegetation period. During the vegetation period, N2O losses and yields were significantly different between the three forage crops. The unfertilised clover plot produced the highest yields and the lowest N2O losses on this soil compared to the highly fertilised ryegrass plot. Total N2O losses from soil under spring barley were higher than those from soil under the forage crops; this was mainly a consequence of N2O emissions after the incorporation of the forage crop residues.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photoreduction of methyleneblue by N-methyl-9-phenylacridane (ACH) is studied in acetonitrile by means of flash photolysis and quantum yields. In the first step, due to fast proton shift within the original electron transfer product protonated semi-methyleneblue MBH.+ and the deprotonated donor radical (N-methyl-9-phenylacridanyl radical AC·) are formed with a rate constant of 2×108 M-1 s-1. In this radical pair a second electron is transferred very fast from AC· to MBH.+ with a rate constant ke2 ≈ 1010 s-1 to form leuco-methyleneblue and N-methyl-9-phenyl-acridinium salt (AC+). About 80% of the two-equivalent reduction product, leuco-methyleneblue, are formed within the first solvent cage during the flash. The maximum quantum yields of photoreduction approach ϕisc of MB+ as expected for a two-equivalent reduction reaction.The out-of-cage reaction consists of the known disproportionation of the protonated semi-methyleneblue MBH.+ and its reduction by the N-methyl-9-phenylacridanyl radical AC·. From the decay kinetics kred = 3×109 M-1 s-1 and kdis = 8×108 M-1 s-1 is derived.The system sensitizes the dediazoniation of p-N,N-dimethylamino benzenediazonium tetrafluoroborate efficiently even at very low diazonium salt concentrations (Φ = 0.6).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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