Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
101 (1994), S. 3852-3856
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Nonadiabatic Xe+(2P1/2) electronic fine structure relaxation by collision with several gases has been investigated using a monitor method at temperatures near 4 K. Of the several collision partners, only CH4 and N2O exhibited measurable spin–orbit relaxation rates of 6.1×10−10 and 1.2×10−10 cm3 s−1, respectively. Both CH4 and N2O possess parallel exothermic charge transfer and electronic quenching channels which may suggest a sequential two electron charge transfer channel facilitated electronic relaxation mechanism.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.468465
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