ISSN:
1573-9171
Keywords:
synthesis
;
hypercoordinated organogold(I) compound
;
secondary bonds
;
diphenylmethane
;
X-ray diffraction analysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Cyclic organogold $$| \overline {Au(o - C_6 H_4 )CH_2 (C_6 H_4 - o)Au(\mu - PPh_2 CH_2 CH_2 } \mathop P\limits^| Ph_2 )$$ complex, containing an Au...Au bond, was prepared by reaction of Ph3PAu(o-C6H4)CH2(C6H4-o)AuPPh3 with dppe. The length of the carbon bridge of the diphosphine ligand, optimal for formation of the Au...Au bond, was preliminarily determined using molecular simulation. The structure of the complex obtained was determined by X-ray diffraction analysis and by MS,1H NMR, and31P NMR.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00707234
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