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  • 1
    ISSN: 1090-6487
    Keywords: 33.50.Dq ; 44.40.+a
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal luminescence spectra of a dense, nonuniformly heated resonance medium (sodium vapor) are investigated experimentally under conditions when the resonance corrections to the relative permittivity are not small compared to unity and the photon mean free path is comparable to the wavelength of the radiation. The shape of the recorded spectra agrees well with a previously developed general theory of resonance radiation transfer which predicts a strong asymmetry of the spectra. The prospects for performing more-sensitive measurements in order to make a quantitative check of the theoretically predicted anomalous intensity (an order of magnitude higher than in the standard theory of resonance radiation transfer) of the radiation from a dense nonuniform medium are discussed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1090-6487
    Keywords: 52.25.Rv ; 51.70+f
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The purely thermal infrared emission spectra of a resonance medium (sodium vapor) are investigated experimentally. It is shown that the emission intensity in the 2–3 μm range at temperatures of 600–1200 K is several orders of magnitude higher than the intensity obtained from the standard theory of resonance radiation transfer. This phenomenon can be conventionally termed an “infrared catastrophe.” The form of the recorded spectra and the absolute intensity of the emission in both the infrared and visible regions of the spectrum are in agreement with the theory developed by Yu. L. Zemtsov and A. M. Starostin, Zh. Éksp. Teor. Fiz. 103, 345 (1993) [JETP 76, 186 (1993)], in which the Boltzmann spectral distribution of the population of the resonance level is proportional to exp(−ħω/T).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of experimental and theoretical physics 84 (1997), S. 703-715 
    ISSN: 1090-6509
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An experimental investigation and numerical simulation of resonant laser breakdown are performed. As a result, quantitative agreement between the experimental data on the parameters of a dense resonant plasma (the electron density and the electron temperature) and the results of calculations in the range of detunings of the laser radiation from resonance Δλ〉2–2.5 nm, in which the spatial instability of the intense resonant laser beam and the absorption of radiation are minimal, is obtained for the first time. It is shown that the previously proposed mechanism of resonant breakdown associated with laser-induced associative ionization introduces only a small correction to the final extent of ionization of the resonant plasma and scarcely alters its temperature. The influence of quantum stimulated inverse bremsstrahlung processes, which are usually described as collisions of the second kind in the resonance case, on the energy gain by electrons is analyzed for the first time in reference to specific experimental findings. The numerical calculations show that at detunings of the order of the Rabi frequency, the mechanism by which electrons gain energy through the resonant system does not reduce to collisions of the second kind and can significantly increase the density of the resonant plasma. However, in this range of detunings the laser beam is still strongly perturbed by instability processes, precluding a proper comparison of the theory with experiment. At large Δλ the classical and quantum cases differ from one another only slightly, and the values of N e calculated for both mechanisms lie within the measurement error.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of experimental and theoretical physics 87 (1998), S. 76-86 
    ISSN: 1090-6509
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The purely thermal visible and infrared radiation emitted by a dense resonant medium (sodium vapor) heated nonuniformly to temperatures of 600–1200 K was investigated experimentally for the first time under conditions where the photon mean free path is comparable with the emission wavelength. The profile of the recorded spectra and the absolute luminescence intensities in the different spectral ranges show good agreement with the results of a numerical simulation using a previously developed theory of resonance radiation transport which assumes a Boltzmann spectral distribution of the resonant level population proportional to exp(−ℏω/T). The self-reversed resonant sodium line exhibited strong asymmetry and it was shown that under certain conditions, the luminescence spectrum of the medium may exhibit an additional broad peak on the far “red” limb of the resonance line. Calculations and measurements demonstrated that the intensity of the thermal emission of sodium vapor at this red peak is several orders of magnitude higher than that obtained from the standard theory of resonance radiation transport. This effect is arbitrarily termed an infrared “ catastrophe.” It is noted that in a solar corona plasma and in gas-discharge lamps, the far red limbs of the resonant lines may make a substantial contribution to the total luminescence intensity and in some cases, considerably exceed the intensity of the photorecombination and bremsstrahlung continuum.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1090-6533
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The optical absorption spectra of high-density (1016–1019 cm−3) sodium vapors were studied in a broad spectral range (0.35–1.1 μm). The intensity of thermal radiation from sodium vapors was measured in the 2–3 μm wavelength interval. It is established that the effect of metal clusters can account neither for the observed structure of absorption spectra nor for the increased intensity of emission in the near-IR range reported in some works (in particular, for the emission spectra of high-pressure gas-discharge sodium lamps).
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 31 (1982), S. 1034-1035 
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Conclusions Exhaustive chlorination is observed when chlorine fluosulfate is reacted with 1,3,5-trichlorobenzene and nitrobenzene under mild conditions.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Russian chemical bulletin 30 (1981), S. 2194-2197 
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Conclusions The reaction of peroxydisulfuryl difluoride with nitro-, chloronitro-, and ethylnitrobenzenes gave the previously unknown fluorosulfates, in which connection the ethylnitrobenzenes are substituted in the nucleus under these conditions.
    Type of Medium: Electronic Resource
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