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  • 1
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The brittleness of polystyrene (PS) and the toughness but notch sensitivity of polycarbonate (PC) have been studied by the detailed finite element analyses of the stress and strain fields in a notched tensile bar with a minor defect. The defect represented a flaw or imperfection, generated during the test specimen production. The large-strain mechanical responses of both materials were approximated by an accurate elasto-viscoplastic constitutive model with appropriate material parameters. It was assumed that failure occurs instantaneously once the dilative stress exceeds a certain critical craze-initiation stress. The analyses show that the unstable post-yield mechanical response of both materials results in localisation of stresses and strains near the defect at a very low macroscopic strain (0.16%). As a result, a strong dilative stress concentration is formed just below the surface of the defect. For the polystyrene specimen, the critical stress is reached at the defect. For the polycarbonate, however, the effect of the stress concentrating defect was counteracted by a higher craze-initiation stress and stronger strain hardening. The PC craze-initiation resistance, however, did not suffice to overcome the dilative stress concentration raised by the notch tip.
    Materialart: Digitale Medien
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  • 2
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The influence of microstructural properties on the macroscopic mechanical behaviour has been studied by finite element predictions of the response of different microstructures of polystyrene (PS) or polycarbonate (PC) containing voids or rubbery particles, subjected to unidirectional extension. The voids represent a low-modulus non-adhering dispersed phase. The rubbery inclusions, which are assumed to be pre-cavitated and perfectly adhering, idealise core-shell particles with a hard rubber shell and a soft non-adhering or pre-cavitated core. The predictions show that the inclusion properties strongly affect the averaged post-yield response of the heterogeneous systems. Especially the post-yield strain softening can be eliminated by the introduction of voids in PC or rubbery particles in PS. Since macroscopic strain softening is believed to be the main cause of catastrophical stress or strain localisations, the softening elimination is believed to be primarily responsible for toughness enhancement of the polystyrene or polycarbonate systems. The results and experiences are extrapolated in order to explain the influence of the absolute length scale of a sub-micron sized morphology on the macroscopic behaviour, especially toughness. Two potential sources of particle-size effects are presented that may result in a stabilised, and thus tougher, macroscopic mechanical response, i.e. the yield stress reduction near a surface or interface because of a locally enhanced mobility of the polymer segments, and the temporary excessive hardening because of a sufficiently small size of the yield zones which results in a reduced effective entanglement distance. The paper concludes with a discussion on the extension of this knowledge to all other, for the moment amorphous, polymers.
    Materialart: Digitale Medien
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  • 3
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The deformation behaviour of heterogeneous tensile bars is investigated by using the recently developed multi-level finite element method (MLFEM) that allows for a numerical coupling between the microscopic and macroscopic stress-strain behaviour, combined with an accurate elasto-viscoplastic constitutive model (single-mode compressible Leonov model) and a detailed finite element model of the microstructure. The method is used to predict the influence of the microstructure on localisation phenomena in plane strain notched and hour-glass-shaped polycarbonate and polystyrene tensile specimen with different volume fractions of non-adhering or adhering rubbery particles. In Part I and II of this series it was already suggested that elimination of the unstable post-yield strain softening behaviour of a polymeric material by appropriate microstructural modifications may be essential for toughening. The results of the multi-level analyses presented in this paper confirm this statement. It is shown that a stable post-yield response, resulting from microstructural adaptations, is indeed a prerequisite for the distribution of plastic strains over the whole macro- and microstructure: massive shearing is promoted by the introduction of voids in the polycarbonate or load bearing pre-cavitated rubbery particles in the polystyrene. Furthermore, it is shown that the voids indeed reduce the macroscopic dilative stresses to safe values. The results suggest that localisations of strain and stress will always occur on a macro and/or micro level. Catastrophic failure, however, can be postponed by stabilisation of the post-yield behaviour of the material and reduction of the macroscopic dilative stresses through appropriate microstructural adjustments.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 479-487 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The performance of screws of advanced design in injection molding has been investigated with respect to four different objectives: (1) improvement of distributive mixing; (2) improvement of dispersive mixing; (3) increase of plasticating capacity; and (4) reduction of inhomogeneity of melt temperature.The screws used are three zone screws with different compression ratios, screws with pineapple or Maddock/Egan mixing elements, with one or two channel barrier sections, with static mixers mounted in the valve or in the nozzle, or with combinations of these different elements. The best mixing quality is obtained with multi-channel Maddock sections. The highest plasticating capacity and, consequently, the shortest cycle times are achieved with the barrier screws. Temperature measurements show that these screws improve melt homogeneity considerably with a relatively small loss of plasticating time. In all cases, increasing the back pressure gives inferior results compared with improvement of the screw design.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 893-904 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The Buss cokneader is a single-screw extruder with interrupted flights. Pins from the barrel are inserted into the screw channel. The screw is both rotating and oscillating. Due to this action, screw flights are continuously wiped by the pins. During one passage of the pin, the material is not only subjected to high shear stress, but it is reoriented as well, thus promoting the distributive mixing process by the local weaving action of the pins and screw flights. Attempts to model the cokneader tend to focus on a single pin passing through the hole in a screw flight (1, 2). However, a more comprehensive model can start with the same equations that apply to the corotating twin-screw extruder (3). Because the effect of leakage flows on the local pressure gradient has to be considered along with the effect of the local dragging action of the pins (neglecting the oscillatory action), experiments with model liquids have been performed to evaluate the comprehensive model. Additional experiments with a Plexiglas-wailed cokneader support the calculations concerning filled lengths in various screw geometries. These results, and those of model calculations, which are extended to the nonisothermal, non-Newtonian situation, are presented.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 758-772 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Slip at boundaries is possible in viscous flows; for instance, in the extrusion of foodstuffs, water-containing materials, and some polymers. There are two phenomenological descriptions of slip: The first is based on the presence of a very thin, low viscosity boundary layer and has been derived for capillary flow and extrusion; the second is based on a Coulomb-friction mechanism and has been derived for capillary flow only. After a survey of these results, the friction model is derived for the extrusion process. All calculations are as simple as possible: two-dimensional, Newtonian, isothermal, and with constant boundary layer parameters of coefficients of friction. A strong dependence of pumping characteristics and efficiency on the slip boundary conditions, and also on the extruder length in the case of friction, was found, especially when slip is only allowed for at the screw surface. Exercises like these may help in understanding abnormal extrusion behavior of slippery materials in practice.
    Zusätzliches Material: 29 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 1539-1544 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A detailed rheologicai analysis over large shear rate intervals has been performed for electron-beam-irradiated blends of polypropylene (PP) and ethylenepropylene-diene monomer (EPDM) rubber. At high frequencies, a lower viscosity results from irradiation compared with unirradiated blends, which implies that the irradiated blends are easily processable via injection molding. At low shear rates, however, the irradiated blends behave like a network, and the viscosity may even exceed the viscosity of the unirradiated blends. This particular behavior can result in the formation of weak weld lines. Aggregation of the dispersed, cross-linked EPDM particles into a skeletal structure is the most probable explanation. In a first attempt, it was tried to correlate the network behavior to the average (shortest) interparticle distance (ID) between two rubber particles, which takes into account both volume fractions and particle size of the dispersed phase. Provided that the EPDM rubber is sufficiently cross-linked, the network behavior becomes more pronounced; i.e., increase in viscosity with decreasing interparticle distance. Above a critical value of the ID, the viscosity does not change and is determined by the PP matrix. As a vast amount of literature indicates, the rheology of blends proves to be difficult to understand. Because of the more stable morphology, compared with usual blends, induced by irradiation, a more valuable interpretation of the rheological behavior is possible.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 352-359 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A number of recent screw designs is analyzed for melting performance, using a simple analytical approach based on Tadmor's original work. The melting length for a screw with constant depth channel is used as reference. An ideal compression screw will have a melting length of one-half the melting length of the reference screw. The Maillefer melt separation principle is discussed. The Maillefer screw melts in 2/3 of the length of the reference screw. Screws by Barr, by Dray and Lawrence and by Kim are shown to approach the ideal compression screw. A new design screw, using ideal compression and multiple channels and having a very large screw pitch, is shown to be a considerably more efficient melting device than any of the other, screws discussed.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 275-290 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: In many operations in polymer processing, such as polymer blending, devolatilization, or incorporation of fillers in a polymeric matrix, continuous mixers are used; e.g., corotating twin-screw extruders (ZSK), Buss Cokneaders and Farrel Continuous Mixers. Theoretical analysis of these machines tends to emphasize the flow in complex geometries rather than generate results that can be directly used (1-5). In this paper, a simple model is developed for the hot melt closely intermeshing corotating twin-screw extruder, analogous to the analysis of the single-screw extruder carried out in 1922 and 1928 (6, 7). With this model, and more specifically with its extension to the complete nonisothermal, non-Newtonian situation, it is possible to understand the extrusion process and to calculate the energy, specific energy, and temperature rise during the process with respect not only to the viscosity of the melt, but also to the screw geometry (location and number of transport elements, kneading sections and blisters, pitch, positive or negative, screw clearance, and flight width) and screw speed. To support the theoretical analysis, model experiments with a Plexiglas-walled twin-screw extruder were performed, in addition to practical experiments with melts on small- and large-scale extruders, with very reasonable results, In Part 2, the Buss Cokneader will be analyzed analogously.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 1156-1161 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: In the previous paper (1) the melting performance of a number of recent screw designs was analyzed, using a rather simple theory. A new screw design was proposed. Here the results of more elaborate calculations, are given in which the influence of the flight clearance and of a shear-thinning temperature dependent viscosity are investigated. The former conclusions are not altered in essence by these effects. Experimental results with a prototype screw are presented, showing that melting capacity is increased. Up to 100 percent increase in throughput is possible in the high RPM range (in comparison with a much longer traditional compression screw), provided that the feed capacity is sufficient. This usually requires the use of a grooved, well-cooled, feed section; the capacity of such a feed section depends, for a given screw geometry, on channel depth and granule dimensions. The melt leaves the melting section at a relatively low temperature. The melting section only melts the material and does not raise, its temperature unnecessarily. A further step towards separating distinct tasks of the extruder by functional screw design has been made.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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