ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The complete crystal structure of C10H19NH2, HCl,1½, H2O has been established by three-dimensional methods (PATTERSON synthesis, BUERGER's minimum function, FOURIER syntheses and refinement by least square methods). The carbon skeleton of the molecule has almost the symmetry C2h- 2/m. Its conformation and dimensions (bond lengths and angles) are almost identical with those of 1,6-trans(and cis)-di-aminocyclodecane dihydrochloride. It is significantly different from the («crown») Y-model, assumed earlier Hydrogen bonds between the ring, the HC1 and H2O molecules build up a double layer // (100); these layers are only connected by VAN DER WAALS' forces, and not by direct strong bonds.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19640470522
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