ISSN:
1588-2780
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Energy, Environment Protection, Nuclear Power Engineering
Notes:
Abstract The reaction of [TcNCl2(PPh3)2] with 2,2′:6′,2″-terpyridine producedcis-[TcNCl2(terpy)] selectively. The resulting complexes were characterized by1H NMR and IR spectroscopy. The geometries of thecis andtrans isomers were estimated by theoretical calculations following a density functional method. Thecis isomer is likely more stable than thetrans one with respect to thetrans influence of the nitrido ligand. Furthermore, the behavior of nitridotechnetium complexes in polar solvents was compared to Os-analogues.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02349519
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