ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. In acetone or ethyl acetate, cis-[PtH(SnX3)(PPh3)2] is formed at the first stage of the reaction between [PtHX(PPh3)2] and SnX2; in inert solvent the trans-isomer is the reaction product. 2. With increase in temperature, redistribution of the phosphine ligands in cis-[PtH-(SnX3) (PPh3)2] takes place, and [PtH(PPh3)3]+, trans-[PtH(SnX3)2(PPh3)]−, and a platinum complex without phosphine are formed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00949943
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