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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 263 (1985), S. 328-334 
    ISSN: 1435-1536
    Keywords: Melt rheology ; network transition ; molecular weight distribution ; Doi-Edwards theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The molecular theory proposed by Doi and Edwards is applied to the determination of the rheological behaviour of a technical polystyrene with medium molecular weight and rather broad molecular weight distribution. The molecular parameters of the polystyrene were measured by means of the GPC method. The rheological properties of the sample were investigated by means of a dynamic viscometer. It is shown that a good description of the linear viscoelastic properties of the melt of the polystyrene can be given using the Doi-Edwards theory combined with a mixing rule of simple superposition of the moduli according to the number fractions of the molecular weights.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 14 (1975), S. 581-590 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Zusammenfassung Numerische Formeln werden gegeben, die die Berechnung des Spannungsrelaxationsmoduls aus dem dynamischen Modul ermöglichen. In diesen Formeln treten Werte des Speichermoduls und Verlustmoduls auf, die bei logarithmisch äquidistanten Frequenzen gemessen wurden. Das Verhältnis zweier aufeinanderfolgender Frequenzen entspricht stets einem Faktor 2. Für alle Formeln werden obere und untere Schranken für den relativen Fehler abgeleitet. Diese Schranken hängen vom Werte der Dämpfung (tanδ) ab, die bei der Kreisfrequenzω 0 auftritt, für die die Berechnung erfolgt. Die Berechnung des Relaxationsmoduls ist um so einfacher, je niedriger der Wert der Dämpfung ist. Zu dieser Berechnung benötigt man entweder den Wert des Speichermoduls bei der Kreisfrequenzω 0=1/t und die Werte des Verlustmoduls in einem ziemlich engen Frequenzintervall umω 0, oder den Wert des Speichermoduls bei der Kreisfrequenzω 0 und den Wert der logarithmischen Frequenzableitung des Speichermoduls in einem Frequenzintervall umω 0.
    Notes: Summary Numerical formulae are given for calculation of stress relaxation modulus from the known course of the storage and loss modulus with frequency for linear viscoelastic materials. The formulae involve values of the storage modulus and/or loss modulus at frequencies equally spaced on a logarithmic frequency scale, the ratio between successive frequencies beeing two. A method is introduced by which bounds for the relative errors of these formulae can be derived. These bounds depend on the value of the damping, tanδ, at the angular frequency,ω, for which the calculation is made. The less the damping, the simpler the calculation of the stress relaxation modulus. This calculation involves either the value of the storage modulus at a frequencyω 0 = 1/t, and the values of the loss modulus in a rather narrow frequency region aroundω 0, or the value of the storage modulus at frequencyω 0 and the derivative of the storage modulus with respect to the logarithm of frequency in a frequency region aroundω 0.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 30 (1991), S. 300-300 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 26 (1987), S. 375-384 
    ISSN: 1435-1528
    Keywords: Torsional creep ; creep recovery ; time-temperaturesuperposition ; recoverable compliance ; polystyrene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The torsional creep and recoverable bahaviour of a technical polystyrene is reported over seven orders of magnitude of the value of the compliance from 10−8 to 10−1 Pa−1 and over more than seven decades in time. The results for the recoverable compliance JR (t) reveal a dispersion region seen between the glass transition and the steady-state recoverable compliance Je. The limiting value of the final dispersion Je = 4.7 · 10−4 Pa−1 indicates a broad molecular-weight distribution. The steady-state recoverable compliance Je is independent of the temperature. The temperature dependence of the final dispersion was found to be indistinguishable from that of viscous flow. However, this temperature dependence differs significantly from that of the glass-rubber transition. A proposal has been made for the construction of creep compliance and recoverable compliance over an extended time scale.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 252 (1974), S. 759-759 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 267 (1989), S. 39-47 
    ISSN: 1435-1536
    Keywords: Volumerelaxation ; free volume ; one-parametermodel ; multiparametermodel ; singletemperaturejump
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The theory of volume relaxation, based on free volume, is briefly reviewed. Emphasis is placed on demonstrating the necessity of the introduction of a retardation time spectrum for the description of the volume relaxation behavior. For simple approach experiments after a single temperature jump from equilibrium, a comparison between experiment and theory is made, using a one-parameter model as well as a multiparameter model. In the case of isothermal contraction, a good description is obtained for both models in a temperature range down to 50 K belowT g. Extending the investigations to isothermal expansion experiments, it becomes necessary to use the multiparameter model.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 13 (1974), S. 209-215 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Summary Two compounds or rigid PVC, one of the emulsion type, the other of the suspension type, were processed at different temperatures by means of a highly instrumented 30-mm research extruder. During processing, measurements were made of the axial distribution of pressures and temperatures at the inner wall of the barrel, of the axial temperature distribution in the hollow screw and of the radial temperature distribution of the melt close to the screw tip. The melts were forced through capillaries and slit dies and their viscosity behaviour was measured. Extrudates were subjected to an immersion test in acetone, in which they showed very significant differences in behaviour that depended on the temperatures at which they were processed. These differences did not show up in impact strength or yield strength in stress strain testing.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 33 (1994), S. 530-541 
    ISSN: 1435-1528
    Keywords: Glass transition ; discrete retardation spectrum ; terminal transition ; entanglement transition ; recovery
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract An algorithm for the calculation of discrete, logarithmic equidistant retardation spectra from creep or recovery is applied to experimental data in different regions of consistency. Spectra in the glass-rubber transition region are given for technical poly(styrene), poly(methylmethacrylate), and poly(carbonate) as well as the course of all characteristic compliance type functions. The spectrum in the terminal region of a poly(styrene) of narrow molecular weight distribution is calculated both from creep and recovery data. The course of the dynamic moduli calculated from the spectra and by direct conversion is found in excellent agreement to measurements by means of a dynamic viscometer.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 5 (1966), S. 261-261 
    ISSN: 1435-1528
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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