ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The binuclear hydroxo complexes [{M(C6F5)2(μOH)}2]2−(M=PdandPt)reactwithN-substituted salicylaldimines (HSal=NR) or β-ketoimines (RN=CMeCH2COR′) to give the corresponding N-substituted salicylaldiminato or β-ketoiminato mononuclear complexes, [M(C6F5)2(Sal=NR)]− (M=Pd or Pt; R= Me, Et, Ph, o-MeC6H4, p-MeC6H4 or p-ClC6H4) or [(C6F5)2M{N(R)C(CH3)CHC(O)R′}]− (M=Pd or Pt; R=o-MeC6H4 or p-MeC6H4; R′=Me or Ph), respectively. The complexes have been characterized by partial elemental analyses, conductance measurements and spectroscopic (i.r. and 1H and 19F- n.m.r.) methods.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1018571531737
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