Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
18 (1986), S. 791-800
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The rate of decarbonylation of the hydroxyacetyl radical in acetonitrile is measured by effect modulated ESR spectroscopy and found to be log (KD/s-1) = (11.0 ± 1.5)-(2.3RT)-1 (37 ± 8)kJ/mol. The result is shown to be reasonably well connected with a variety of decarbonylation data known for other acyl species by asimple Evans-Polanyi relation.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180706
Permalink
Library |
Location |
Call Number |
Volume/Issue/Year |
Availability |