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  • 1
    Electronic Resource
    Electronic Resource
    On the rates of decarbonylation of hydroxyacetyl and other acyl radicals (1986)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 18 (1986), S. 791-800 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rate of decarbonylation of the hydroxyacetyl radical in acetonitrile is measured by effect modulated ESR spectroscopy and found to be log (KD/s-1) = (11.0 ± 1.5)-(2.3RT)-1 (37 ± 8)kJ/mol. The result is shown to be reasonably well connected with a variety of decarbonylation data known for other acyl species by asimple Evans-Polanyi relation.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550180706
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