ISSN:
1572-9540
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The extremes of single ion slow paramagnetic relaxation and cooperative 3D-antiferromagnetic order are exemplified in a series of structurally characterized complexes based on the anhydrous FeCl3-α-di-imine system. “Soft” Cl−Cl contacts, C−C (π-π) and hydrogen bonding interactions are found to lead to surprisingly strong magnetic exchange among five and six coordinate high-spin iron III monomers. The latter form the building blocks of novel “double chain” polymer magnets held together via the preceding “weak” interactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02405502
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