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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 41 (1988), S. 859-862 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mossbauer spectroscopy and X-ray diffraction techniques were used to investigate the iron oxides and other mineral phase developments in calcareous and noncalcareous soil samples after firing at ≈ 1000°C. Well crystalline haematite with larger particle size was produced in the fired non-calcareous soil. On the other hand, while goethite in the strongly calcareous natural material was transformed into haematite at the oven drying temperature, non of the latter was detected after firing at 1050°C. This could be related to the reaction between CaO, quartz and aluminosilicates at 800°C to produce calcium aluminosilicates which may have hindered the growth of haematite above this temperature.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 57 (1990), S. 2179-2186 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mössbauer spectra of triclinic Fe2P2O7 indicate the existence of two crystallographic metal positions in the structure. In the paramagnetic region the two Mössbauer doublets are closely overlapping. The magnetic transition takes place at ≈ 21 K and the saturated fields are around 12 tesla for the two positions. In monoclinic Fe2P4O12 the two octahedrally coordinated metal positions give quite different quadrupole splittings (1.5 and 3 mm/s at room temperature) and hyperfine field values (42 and 12.5 Tesla at 5 K). The transition temperature is at ≈ 18.5 K.
    Type of Medium: Electronic Resource
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