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  • 1
    Electronic Resource
    Electronic Resource
    Trace determination of low molecular weight aliphatic amines in air by gas chromatograph (1983)
    s.l. : American Chemical Society
    Analytical chemistry 55 (1983), S. 2199-2201 
    Details
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ac00263a046
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Effect of cathodic reduction on catalytic activity of amorphous alloy electrodes for electrooxidation of sulfite (1995)
    Springer
    Journal of applied electrochemistry 25 (1995), S. 953-961 
    Details
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Active electrode materials for a new zinc electrowinning process, in which the thermodynamic cell voltage is about half that of the conventional process by replacing oxygen evolution by anodic oxidation of SO2 produced in the zinc smelting process have been studied. Immersion in HF solution and subsequent cyclic voltammetry (CV) in sulfuric acid are known to be effective surface activation treatments of the amorphous alloy electrodes. The galvanostatic cathodic reduction (CR) treatment was applied to obtain further activation for sulfite oxidation for HF- and CV-treated electrodes prepared from amorphous nickel-valve metal-platinum group metal alloys. This treatment has been found to be effective in enhancing the activity. Among the amorphous Ni-40Nb alloys containing platinum group elements, the platinum-containing electrode showed the highest catalytic activity, which was higher than that of platinized platinum. Furthermore, the electrocatalytic activities of CR-treated electrodes prepared from amorphous alloys containing platinum and rhodium, and platinum and ruthenium were higher than that of the electrode containing only platinum. According to XPS analysis of the amorphous Ni-40Nb-1Pt-1Ru alloy specimen the enrichment of platinum and ruthenium occurred by CV treatment, and a small amount of oxidized platinum and ruthenium species remained on the electrode surfaces, but most of them were cathodically reduced to the metallic state by CR treatment. High catalytic activities for sulfite oxidation can be attributed to the metallic state of platinum and ruthenium contained in the alloy electrodes, even though the activity of these electrocatalysts is higher than that of pure Pt or Ru.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00241590
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Surface activation of manganese oxide electrode for oxygen evolution from seawater (1997)
    Springer
    Journal of applied electrochemistry 27 (1997), S. 1362-1368 
    Details
    ISSN: 1572-8838
    Keywords: manganese oxide electrode ; oxygen evolution ; seawater electrolysis ; surface activation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Utilizing the fact that the equilibrium potential of oxygen evolution is lower than that of chlorine evolution, oxygen evolution in seawater electrolysis was enhanced by decreasing the polarization potential under galvanostatic conditions through increasing the effective surface area of manganese oxide electrodes. Electrodes were prepared by a thermal decomposition method. IrO2-coated titanium (IrO2/Ti electrode) was used as the substrate on which manganese oxide was coated (MnOX/IrO2/Ti electrode). Subsequently, oxide mixtures of manganese and zinc were coated (MnOX–ZnO/MnOX/IrO2/Ti electrode). The effective surface area of the MnOX–ZnO/MnOX/IrO2/Ti electrodes was increased by selective dissolution of zinc (leaching) into hot 6M KOH. The oxygen evolution efficiency of the MnOX/IrO2/Ti electrode was 68–70%. Leaching of zinc from the MnOX–ZnO/MnOX/IrO2/Ti electrodes with 25mol% or less zinc led to a significant increase in the oxygen evolution efficiency. The maximum efficiency attained was 86% after leaching of zinc from the MnOX–25mol%ZnO/MnOX/IrO2/Ti electrode. However, large amounts of zinc addition, such as 40mol% or more are detrimental because of a decrease in the oxygen evolution efficiency. This is due to the formation of a double oxide, ZnMnO3, which is hardly dissolved in hot 6M KOH.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1018421028624
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Anodically deposited manganese-molybdenum oxide anodes with high selectivity for evolving oxygen in electrolysis of seawater (1999)
    Springer
    Journal of applied electrochemistry 29 (1999), S. 769-775 
    Details
    ISSN: 1572-8838
    Keywords: anodic deposition ; manganese-molybdenum oxide electrode ; oxygen evolution ; seawater electrolysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Manganese-molybdenum oxide electrodes were prepared by anodic deposition on an IrO2-coated titanium substrate at a constant current density of 600Am−2 from baths containing 0.2M MnSO4 and 0–0.1M Na2MoO4 at 90∘C and pH 0.5. These electrodes were characterised for oxygen evolution in the electrolysis at 1,000Am−2 in 0.5M NaCl solution at 30∘C and pH 8 or 12. The most active and stable oxygen evolving anode exhibited 100% efficiency for oxygen evolution, and an efficiency of 98.5% for over 1,500 h at pH 12 and of 96.5% for over 2,800 h at pH 8 of continuous electrolysis. X-ray diffraction measurement and XPS analysis indicated that the deposits consist of a nanocrystalline single γ-MnO2 type phase, and manganese and molybdenum in the deposits are in the Mn4+ and Mo6+ states. The electrochemical studies showed that the manganese-molybdenum oxide electrodes drastically reduced the electrocatalytic activity for chlorine evolution to the undetectable level, resulting in 100% efficiency for oxygen evolution, although the addition of molybdenum slightly increased the oxygen overpotential.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1003492009263
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    Paper (German National Licenses)
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