ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The Mo atom in the title compound, [Mo(CO)4(C12H27O3P)2], lies on an inversion centre and has slightly distorted octahedral geometry, with principal dimensions Mo—P 2.4699 (7), Mo—C 2.027 (4) 2.031 (3) Å, P—Mo—P 180, cis-C—Mo—C 88.7 (2), C—Mo—P 86.12 (10) and 87.27 (9)°. The geometry about the P atom is distorted from tetrahedral, with Mo—P—O angles in the range 108.04 (9)–126.03 (10)° and reduced O—P—O angles in the range 96.71 (13)–106.09 (14)°. The average cone angle for the tert-butyl phosphite ligand is 156°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195007803
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