ISSN:
0749-1581
Keywords:
[Pd(η3-C10H15){(R)(+)-BINAP}](CF3SO3)
;
Three-dimensional solution structure
;
2D NOESY NMR studies
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
2D NOESY, COSY and 31P,1H correlation measurements have been carried out on the optically active β-pineneallyl-(R)(+)-BINAP palladium complex, [Pd(η3-C10H15){(R)(+)-BINAP}](CF3SO3). The ortho protons of the four non-equivalent phenyl rings have been assigned, as have the 15 protons of the β-pineneallyl. The 2D NOE data show selective interactions of the phenyl ortho protons with different sections of the allyl ligand, thereby contributing to our knowledge of the three-dimensional solution structure of this cationic complex.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260290302
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