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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1861-1873 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Volatile species are removed from polymers by devolatilization. Foaming experiments using corn syrup and low-density polyethylene were carried out to investigate effects of volatile content, operating vacuum level and stripping agent in devolatilization. When foaming and rupture occur, a limiting foam volume growth was observed for a polymer regardless of the volatile content and the addition of stripper bubbles. A mathematical model was also developed to study the effect of stripper bubbles in polymer devolatilization. Based on the cell model for bubble growth, a bimodal model for foam growth is developed as the first step to describe the initial formation and growth of the volatile and stripper bubbles in polymer during devolatilization. When foaming and breakup occur at a critical foam volume expansion, a film model for mass transfer is used to model the second step of devolatilization. A numerical factorial study shows that the devolatilization section should be designed and operated to provide the screw channel sufficient free volume and residence time for the desired foam expansion.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1874-1883 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this work, the bimodal/film model is compared with the cell model based on a case study using polystyrene/styrene devolatilization. It shows improvements over the cell model: (1) it requires a lower initial number of bubbles, which is more physically realistic and (2) it takes into account the observation of a limiting foam volume growth for a specific polymer in devolatilization. A stripper dispersion experiment was designed to investigate the effect of dispersed nitrogen stripper bubbles on the foam dynamics and devolatilization efficiency. The variables examined include polymer viscosity, initial volatile concentration, and the initial number and size of dispersed stripper bubbles. Polymer viscosity was the dominant factor in limiting the maximum foam volume expansion. The number and size of dispersed stripper bubbles show positive and negative effects (which are only secondary) on the maximum foam volume expansion, respectively. The initial volatile concentration has no effect on limiting the maximum foam volume expansion.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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