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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 522-523 (Aug. 2006), p. 461-468 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The behavior of the surface oxide scale on steel products during hot rolling processinfluences the surface properties of final products. To investigate the deformation and the fracturebehavior of surface oxide scale of Fe-13Cr alloy, a hot rolling test was carried out. The oxide scalerolled out was observed in detail by using TEM. The specimen was hot-rolled after oxidation at1100[removed info] for 90 minutes in air. The hot rolling tests with two conditions ([removed info]. The hot rolling test ofthe outer scale {=whole layer scale} , [removed info]. The hot rolling test of the inner scale that removed theouter scale) were carried out. The rolling reduction rate was 25, 44, 58, and 68%. The outer scalewas composed of Fe2O3 and F3O4, and the inner scale was composed of Fe3O4, FeCr2O4, and a smallamount of Fe2SiO4. Fe2SiO4 formed along the grain boundaries of the other oxides (Fe3O4, FeCr2O4)was observed by TEM. In the test [removed info], Fe2O3 of the outer scale was pulverized to fine particle thatlooks like red powder, and Fe3O4 of the outer scale was cracked by hot rolling. A ductility-likebehavior was observed in the inner scale (Test [removed info]). That is, it was found by the SEM observationthat porosity and micro cracks of the surface oxide disappeared gradually according to the increasein the rolling reduction. It was thought that the porosity and the micro cracks eased the compressionstress caused by hot rolling. In the case of high reduction rate, FeSi2O4 ,which is a low melting pointoxide, formed on grain boundary caused grain boundary slipping. When the rolling reduction is veryhigh, plastic deformation by dislocation occurred in Fe3O4 and FeCr2O4. However, these oxideswere broken, when their plasticity would not be able to accept considerably high rolling reduction
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 369-372 (Oct. 2001), p. 555-562 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 46 (1990), S. 723-726 
    ISSN: 1420-9071
    Keywords: TRH ; new antibody ; carbodiimide coupling method ; enzyme immunoassay ; immunohistochemistry ; rat ; hypothalamus ; magnocellular groups
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary We produced a new type of antiserum to thyrotropin-releasing hormone (TRH) in rabbits. The immunogen is TRH-BSA, the production of which is based on the formation of an amide bond using carbodiimide (EDC). The specificity of the antiserum was assessed by enzyme immunoassay (EIA) and immunohistochemistry. When using the anti-TRH serum for immunohistochemistry in rat hypothalamus, new magnocellular groups were detected in the ventrolateral parts of the posterior hypothalamus and the dorsal parts of the third ventricle. Colchicine treatment was found not to be necessary to visualize perikarya containing TRH.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1420-9071
    Keywords: Anti-dopamine serum ; rat ; spinal cord ; ventral horn ; electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary It has been thought that the ventral motor column in the rat spinal cord is virtually free of dopaminergic fibers. However, a new dopaminergic terminal plexus was visualized at all spinal levels in the ventral horn using electron as well as light microscopic immunohistochemistry.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 25 (1994), S. 241-255 
    ISSN: 1572-879X
    Keywords: C, CO, and CO2 hydrogenation ; cobalt catalysts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The hydrogenation of C, CO, and CO2 has been studied on polycrystalline cobalt foils using a combination of UHV studies and atmospheric pressure reactions in temperature range from 475 to 575 K at 101 kPa total pressure. The reactions produce mainly methane but with selectivities of 98, 80, and 99 wt% at 525 K for C, CO, and CO2, respectively. In the C and CO2 hydrogenation the rest is ethane, whereas in CO hydrogenation hydrocarbons up to C4 were detected. The activation energies of methane formation are 57, 86, and 158 kJ/mol from C, CO, and CO2, respectively. The partial pressure dependencies of the CO and CO2 hydrogenation indicate roughly first order dependence on hydrogen pressure (1.5 and 0.9), negative first order on CO (−0.75) and zero order on CO2 (−0.05). Post reaction spectroscopy revealed carbon deposition from CO and oxygen deposition from CO2 on the surface above 540 K. The reduction of cobalt oxide formed after dissociation of C-O bonds on the surface is proposed to be the rate limiting step in CO and CO2 hydrogenation.
    Type of Medium: Electronic Resource
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