ISSN:
0749-1581
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1H NMR spectra of the energetic materials α-hexahydro-1,3,5-trinitro-s-triazine (RDX) and the α-, β-, γ- and δ-polymorphs of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) have been obtained in the solid phase. Primary and secondary dipole-dipole interactions can be observed, which allows calculation of the intramolecular H … H distances. The spectra suggest that γ-HMX, the molecular structure of which is unknown, possesses a chair-chair ring conformation similar to that of α- and δ-HMX.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260230305
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