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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 305-315 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The decomposition of nitric oxide at temperatures ranging from 2700 to 3500 K was studied by means of the shock tube. The experimental data were reduced by the method described in a preceding paper and explained consistently by a set of the elementary reactions. The rate constant of the initiation reaction 2NO → N2O + O, which was not well known in this temperature range, was deduced precisely. k1 was one order of magnitude lower than that reported previously in similar shock-tube experiments, and was consistent with results obtained below 2000 K and from the reverse reaction.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 285-304 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Particle times of flight in incident shock flow were determined experimentally by marking several positions of the test gas (mainly Ar) in the shock tube with an infrared emitting gas (NO or CO2). From the local particle velocity, derived from the particle flight times, temperature and pressure changes behind the shock front were evaluated. Several experimental data were found to be correctly described by Mirels's formulations when used properly. The limitations of the formulations are discussed. It is found to be advisable to evaluate boundary-layer effects on shock-tube flow by experiments, rather than theory, in carrying out chemical kinetics studies.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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