ISSN:
1434-6036
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The theory of the energy distribution of atoms scattered inelastically by solid surfaces which was developed previously is applied to various examples. The dependence of the results on a number of parameters is studied in detail. The importance of many phonon contributions as compared to the validity of first order distorted wave Born approximation is considered in particular. It turns out that low energy He atoms scattered by heavy transition metals provide a good example for which one phonon emission (or absorption) dominates. All other noble gases show appreciable many phonon contributions increasing, of course, with increasing mass of the noble gas and temperature of the solid. For heavy noble gases such as Kr and Xe the energy distribution approaches a gaussian, the width of which is due to the thermal and zero-point motion of the lattice. This width is quite large and thus probably masks most of the ‘fine structure’ of the energy distribution occuring in classical trajectory calculations. We have also tried to apply the theory to light diatomic molecules. Although the results are less certain, partly because of the neglect of the internal motion of the molecules and partly because of uncertainties in the interaction parameters, one probably can expect appreciable many phonon effects already for H2 and, of course, more so for N2 and O2. Recent experimental results on the Debye-Waller factor of Ne/Cu can be reproduced with reasonable potential parameters.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01294430
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