ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The reaction of ethylene glycol, 1,4-butanediol, 1,6-hexanediol, 3,6-dioxaoctane-1,8-diol (triethylene glycol), poly(ethylene oxide)s with M̄n = 300,1000 and 3000, or with poly(propylene oxide)s with M̄n = 425 and 2000 in excess with AIBN leads to the corresponding bis(hydroxyalkyl) 2,2′-azodiisobutyrates (1a-i). These initiators are suited to synthesize telechelics. With equimolar amounts of AIBN and 3-oxapentane-1,5-diol (diethylene glycol), poly(ethylene oxide)s with M̄n = 300, 1000 and 12000, poly(propylene oxide) with M̄n = 425, or with poly(tetrahydrofuran) with M̄n = 1000 and 2000 polymeric azoinitiators of structure 2 are formed. Blockcopolymers may be synthesized by means of these polymeric azocompounds.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1977.021780904
Permalink
