ZIB

Hits per page

hit 1 - 1 | 1 hit

Sorting

Electronic Resource

Photohydration reaction of 1-(p-nitrophenyl)-5,5-dimethyl-1,3-hexadiyne (1995)

Baek, Eun Kyung ; Shim, Sang Chul

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 8 (1995), S. 699-705

add to mindlist on the mindlist

Details

ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Irradiation of 1-(p-nitrophenyl)-5,5-dimethyl-1,3-hexadiyne (NDHD) in aqueous sulfuric acid yields conjugated allenyl ketones (1 and 2) and β-dicarbonyl compounds (3 and 4). The products 1 and 2 are primary photoproducts while 3 and 4 are secondary products formed by thermal hydration of the primary photoproducts showing the maximum quantum yield at H0 = -1·0. A mechanism involving a synchronous addition of hydronium ion (H3O+) to a triplet state of NDHD is proposed.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610081102

Permalink

Library	Location	Call Number	Volume/Issue/Year	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit