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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis and characterization of coordination polymers of poly(butanethiooxamide) with cobalt(II), nickel(II), and copper(II) salts (1991)
    s.l. : American Chemical Society
    Macromolecules 24 (1991), S. 5203-5207 
    Details
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ma00018a027
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  • 2
    Electronic Resource
    Electronic Resource
    Aqueous polymerization of acrylamide initiated with the permanganate-L-serine redox system (1985)
    s.l. : American Chemical Society
    Macromolecules 18 (1985), S. 2113-2116 
    Details
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ma00153a006
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  • 3
    Electronic Resource
    Electronic Resource
    Coordination polymers of Zn(II) and N,N'-bis (carboxymethyl) dithiooxamide (1990)
    Springer
    Polymer bulletin 23 (1990), S. 51-56 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Coordination polymers were synthesized using N,N'-Bis (carboxymethyl) dithiooxamide (NN' CMDTO) and Zinc(II) salts. The complexes were characterized by elemental analyses, IR spectral studies, TGA and viscosity measurements. In the proposed structures the ligand was supposed to be coordinated to metal through sulphur and oxygen.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00983963
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  • 4
    Electronic Resource
    Electronic Resource
    Effect of various medium on permanganate - lactic acid initiated polymerization of acrylamide (1980)
    Springer
    Colloid & polymer science 258 (1980), S. 102-105 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary The homogeneous free-radical polymerization of acrylamide initiated by a redox pair permanganate-lactic acid has been investigated at 35 ± 0.2 °C for solutions in water-organic solvents mixture and in aqueous solutions of neutral salts. The iodometric procedure was employed for the kinetic analysis. The experimental results show a considerable effect on the rate of polymerization and molecular weight of the polymer too. The authors are grateful to Council of Scientific and Industrial Research, India for financial assistance rendered to one of them (UDNB).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01474963
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  • 5
    Electronic Resource
    Electronic Resource
    Synthesis and characterization of coordination polymers of Hg(II) with poly(thiooxamides) (1991)
    Springer
    Journal of inorganic and organometallic polymers and materials 1 (1991), S. 417-426 
    Details
    ISSN: 1572-8870
    Keywords: Hg(II) coordination polymers ; poly(thiooxamides) ; thermally stable polymer ; polymer-metal complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Coordination polymers of Hg(II) with dithiooxamide, poly(ethylene thiooxamide), poly(butane thiooxamide), and poly(hexane thiooxamide) have been synthesized. All coordination polymers are solid compounds insoluble in common organic solvents. Coordination polymers have been characterized by elemental analysis, IR spectra, and thermogravimetric analysis and structures have been proposed leading to coordination of metal through S alone as well as N and S both. Thermal stability of the polymers has also been discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00702503
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  • 6
    Electronic Resource
    Electronic Resource
    Permanganate/glycine-initiated polymerization of acrylamide (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1803-1815 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of aqueous polymerization of acrylamide with KMnO4/glycine redox pair was studied in an atmosphere of nitrogen at 35 ± 0.2°C. The rate of polymerization was found to be first power on monomer, activator, and catalyst concentration. The overall energy of activation was calculated to be 15.66 kcal/deg mol (65.54 kJ/mol) between 30 and 50°C. The effects of various additives (alcohols, neutral salts, complexing agents, addition of catalyst) were studied. The dependence of the polymerization rate on the activator and catalyst concentration was studied in DMF-water mixture also. The molecular weight of polymer was determined at various temperatures of the reaction medium.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170220803
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  • 7
    Electronic Resource
    Electronic Resource
    Grafting of acrylamide onto guar gum with the redox system Cu2+/Na2S2O5 (1990)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 41 (1990), S. 577-581 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Propfung von Acrylamid auf Guaran wurde in wäßrigem Medium bei Initiierung mit dem Redoxysystem Cu2+/Na2S2O5 in Gegenwart von Sauerstoff bei einer Temperatur von 35°C durchgeführt. Der Einfluß der Konzentration der verschiedenen Komponenten des Systems sowie der Reaktionstemperatur auf den Verlauf des Pfropfprozesses wurde untersucht. Ein plausibler Mechanismus des Pfropfprozesses wird vorgeschlagen.
    Notes: The grafting of acrylamide onto guar gum in aqueous medium initiated by the redox system Cu2+/Na2S2O5 in presence of oxygen has been studied at the temperature 35°C. The effect of the concentration of the components of the grafting system and of the reaction temperature has been determined. A plausible mechanism of the grafting process is suggested.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1990.010411106
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  • 8
    Electronic Resource
    Electronic Resource
    Grafting of polyacrylamide on to guar gum using K2S2O8 ascorbic acid redox system (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 2187-2204 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The grafting of polyacrylamide on to guar gum in aqueous medium initiated by the potassium persulfate/ascorbic acid redox system has been studied gravimetrically at the temperature 35 ± 0.2°C in the presence of atmospheric oxygen and Ag+ ions. The rate of grafting was found to increase with temperature, concentration of redox components, acrylamide, and guar gum. But at higher concentration of guar gum, the rate of grafting was found to decrease. A mechanism for grafting and suitable rate expression have been suggested.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070391101
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  • 9
    Electronic Resource
    Electronic Resource
    Grafting of acrylamide onto guar gum using KMNO4/oxalic acid redox system (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 1169-1182 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The grafting of acrylamide onto guar gum in aqueous medium initiated by KMnO4/oxalic acid redox system has been studied gravimetrically at the temperature 35 ± 0.2°C. The effect of redox components, acrylamide concentration and quantity of guar gum has been studied in terms of percentage and efficiency of grafting. A plausible mechanism of grafting and a suitable rate expression has been suggested. The rate of grafting was found to increase with increase in temperature and concentrations of redox components and acrylamide, but, at high concentration of guar gum, the rate was found to decrease.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070350504
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  • 10
    Electronic Resource
    Electronic Resource
    Polymerization of acrylamide using mandelic acid/permanganate redox system in acidic medium (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 359-368 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A combined system of potassium permanganate and mandelic acid was found to initiate vinyl polymerization, specifically acrylamide. A study of the reaction kinetics of this system showed that free radicals are formed. The energy of activation was found to be 3.54 kcal/° mol in the temperature range 27-40°C, in nitrogen atmosphere.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070400305
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