ISSN:
0009-2940
Schlagwort(e):
1,3,2,4-Diazadistibetidines, 1,3-di-tert-butyl-
;
Geometrical isomers
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Synthesis, Structure, and Stereoisomerism of 1,3-Di-tert-butyl-l,3,2,4-diazadistibetidinesStarting from 1,3-di-tert-butyl-2,4-dichloro-1,3,2,4-diazadistibetidine a series of 1,3,2,4-diazadistibetidines [R-SbN-ttBu]2 with R = OMe (2), OPh (3), OtBu (4), N(Tms)2 (5), P(Tms)2 (6), Me (7), and tBu (8) has been synthesized. The NMR spectra prove most of the reaction products to be mixtures of geometrical isomers. The structure of trans-tetra-tert-butyldiaza-distibetidine 8a was confirmed by X-ray structure determination.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19901230507
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