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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 90 (1986), S. 842-847 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 89 (1985), S. 711-713 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 34 (1999), S. 4873-4882 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Mechanical testing and surface fractography were used to characterize the fracture of E-glass fiber reinforced epoxy composites as a function of the silane coupling agent used. γ-Aminopropyltriethoxysilane (APS) and δ-aminobutyltriethoxysilane (ABS) were used because these have been shown to have different interfacial mobilities at multilayer coverage. The values of the properties studied generally increased from untreated 〈ABS- 〈APS-treated glass-fiber reinforced composites. Strength and critical energy release rates were more sensitive to the coupling agent used, than the modulus. The flexural strengths of untreated, ABS-, and APS-treated glass-fiber reinforced composites were 449 ± 40, 510 ± 19, and 566 ± 9 MPa (dry state); and 389 ± 23, 459 ± 7, and 510 ± 54 MPa (wet state), respectively. The critical energy release rate, Gc, as determined from a Mode I translaminar fracture toughness tests, for the untreated composites (10.5 ± 0.4 kJ/m2) was lower than that for the ABS-treated composites (14.3 ± 2.1 kJ/m2) which was lower than that for the APS-treated composites (17.1 ± 2.4 kJ/m2). Macroscopic observations showed that a larger fiber debonding area was formed in the crack tip region for the untreated glass composites, suggesting poorer bonding compared to those treated with coupling agents. Since these silanes have similar chemistry, the differences were attributed to differences in the interfacial mobility of the coupling agent layers.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 5231-5238 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effects of interfacial treatment of glass fibres in glass/epoxy composites were studied through Mode I delamination fracture toughness tests using a double cantilever beam specimen. The treatment of glass fibres with two similar silane coupling agents has been shown to improve the mechanical properties of the composite as a function of the type of coupling agent, γ-aminopropyltriethoxysilane (APS) and γ-aminobutyltriethoxysilane (ABS) have similar chemistry, but differ in mobility (molecular motion) at the coupling agent-epoxy interface. The critical energy release rate, G 1c, for the APS-treated composites (0.59±0.05 kJ m−2) was shown to be higher than that of the ABS-treated one (0.37±0.01 kJ m−2) and also the untreated one (0.31±0.02 kJ m−2). In this case, the bulk structural property appears to be a function of the microscopic interfacial properties including the dynamics of the coupling agent layer. Optical characterization of the fracture surfaces reveal delamination at the epoxy-glass interface for the untreated samples, while the ABS- and APS-treated samples showed less interfacial delamination, respectively.
    Type of Medium: Electronic Resource
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