ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, [N3P3(C5H7N2)4(C6H5)2]CoCl2 or [CoCl2(C32H38N11P3)], possesses a five-coordinated CoII atom in an approximately trigonal-bipyramidal geometry. The N3Cl2 donor set of the metal environment comprises two non-geminal pyrazolyl N atoms, one cyclotriphosphazene N atom, and two Cl− ions. The coordination environment and bonding features of the compound are critically compared with related metal complexes of cyclotriphosphazene ligands.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801013253
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