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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 5679-5689 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The following study investigates the microstructural changes induced by shear in dilute suspensions of colloidal Fe2O3 rods (aspect ratio=8.4) using rheo-optic techniques. The large extinction coefficient for the hematite system at the wavelength used (λmax=392 nm) enables rheo-optic experiments on truly dilute suspensions to be undertaken. Optical absorbance spectra have been measured over a range of shear rates for unpolarized light and for light polarized relative to the shear direction. The measured absorbance changes may be attributed to the shear-induced anisotropy in the suspension. Numerical methods are used to obtain solutions of the convective-diffusion equation, which are used to predict the measured change in extinction coefficient with shear for colloidal hematite rods measured using optical rheometry. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 265 (1977), S. 126-128 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Expressions of varying complexity have been proposed to model pseudoplastic behaviour. The Meter model1 contains ?0, ? and two other parameters, tm and a. ? = ? + ?0 - ? / 1 + (t / tm )a-1 (4) tm is the shear stress at which the viscosity ½( ?0 + ? ) and hence is another measurable quantity, a is ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 33 (1994), S. 2437-2442 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 18 (1979), S. 746-751 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 12 (2000), S. 1411-1416 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A torsionally driven cavity is proposed as a suitable mixing device for viscoelastic fluids. "Chaotic" behavior occurs in the secondary flow plane using polyacrylamide Boger fluids due to the inducement of elastic flow instabilities in situations where inertial forces are small. The torsionally driven cavity is also a suitable well-defined geometry for testing the ability of non-Newtonian constitutive models to describe the behavior of elastic fluids in three-dimensional flow as a prelude to solving more difficult mixing problems. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 32 (1993), S. 277-285 
    ISSN: 1435-1528
    Keywords: Brown coal ; suspension ; pipeline ; coal slurry fuel
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The paper describes how the theology of low concentration brown coal suspensions can be exploited to produce high concentration, low viscosity suspensions which are attractive as a potential coal-water fuel. Brown coal suspensions with solid concentrations approaching those of bituminous black coal have been prepared. The high inherent water content (≈ 60 wt %) and macroporosity of the brown coal have been reduced by thermal and chemical means. The hydrophobicity of the coal surface has been increased sufficiently to reduce the tendency for swelling and water uptake. This, together with densification, has allowed the solids content to be progressively improved from 30 wt % solids with raw coal to 65 wt% solids with modified coals while maintaining the viscosity of the suspension at a low level. The high solid concentration was achieved without additives.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1171-1179 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new theoretical approach is proposed for the yield stress of concentrated, flocculated particulate suspensions. Explicit cognizance is taken for the three-dimensional, mechanically rigid particle network held together by interparticle forces wherein the mean coordination number in the assemblage increases and the separation between the particles decreases with an increase in the volume fraction of the solid phase. The Rump-Molerus model relting isotropic normal stress and isotropic normal interparticle force in a bed of single-sized spheres is modified to incorporate the size distribution of particles and extended to the suspension network. The model estimates the yield stress as a function of solids loading for various kinds of size distribution and is in reasonable agreement with experimental data when the surface properties of the particle are held constant.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1894-1903 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The role of swelling clays in hindering the compressional dewatering characteristics of coal-mine tailings is examined. The effects of electrolyte concentration and ion exchange in improving the shear and compressional rheology are compared. Suspensions studies include actual mine tailings (thickener feed and thickener underflow) as well as synthetic clay dispersions made from clay collected from the coal seam. It was shown that the most important parameter in controlling the properties of the tailings suspension is “controlled” dispersion in the presence of a Ca2+ electrolyte concentration in excess of that required to (1) prevent initial swelling and (2) provide full cation exchange of the clay. Under these electrolyte conditions, complete delamination of the clay did not occur, and both the dewatering and handling characteristics of the resultant suspensions improved dramatically.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 1037-1043 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Shear stress and first normal stress difference data are presented for materials which exhibit a constant viscosity and yet at the same time exhibit elasticity levels of the same order as polymer melts. Flow pattern observations in circular die entry flows in conjunction with independent shear and normal stress measurement strongly suggest that these fluids would make excellent model fluids for melt studies. Studies in which the influence of elasticity in the absence of shear thinning and fluid inertia can easily be made. Furthermore it is clearly shown that a realistic solution to the die entry flow problem is not obtained using second order flow theory. In the second order region the secondary cell is observed to be almost identical in size to the cell observed for an inelastic Newtonian fluid in creeping flow. Marked growth in the secondary cell as a function of elasticity is not observed until the shear rates exceed the region of second order behavior. This growth in cell size as a result of elasticity is followed at higher shear rates by a spiraling flow instability like that observed for some polymer melts.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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