ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The dissociation pK values of picric acid, tetrabutylammonium picrate, bromide and hydroxide and tetramethylammonium hydroxide in some 2-methylpropan-2-ol-cosolvent mixtures were determined and correlated with the Taft and Kamlet solvatochromic parameters π*, δ, α and β. The results show the most important solvent properties that affect electrolyte dissociation are polarity, polarizability and hydrogen bond acidity. These results were confirmed by analysis of published literature data.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610071207
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