ISSN:
1572-8854
Keywords:
Copper(II)bis(2,2′-dipyridylamido)
;
CS2 insertion
;
copper(II)bis(2,2′-dipyridyl)-dithiocarbamate
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title compound was obtained from a CS2 solution of bis(2,2′-dipyridylamido)copper(II), by insertion of solvent into this complex. In the structure of the dithiocarbamate the metal atom is approximately square-planar coordinated by four S atoms from two chelating ligands. Considering the long interactions between the metal center and the S(2) atom from a centrosymmetrically related complex [Cu(1)...S(2)=3.230 Å], double bridged dimers are formed with the copper atoms in an elongated square-pyramidal coordination. The crystals are monoclinic, space groupP2 1/n witha=14.549(3),b=11.662(3)c=15.329(4) Å and β=114.79(2)°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01669731
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