ISSN:
1089-7550
Source:
AIP Digital Archive
Topics:
Physics
Notes:
The magnetic properties of Fe[S2CNC4H8]2I have been studied, the first pentacoordinate Fe(III) system of this type with a cyclic terminal group, rather than an alkyl group, to be examined in detail. The susceptibility of a polycrystalline sample is of Curie–Weiss form above 30 K, with g¯=2.16 ±0.02 and S=3/2 and with θ=−0.75±1.0 K. Thus the unusual intermediate spin state occurs here as in earlier examples. The susceptibility can be fit quite well down to about 6 K assuming that axial and rhombic crystal field distortions occur, represented by D[Sˆ2z − S(S + 1)/3] and E[Sˆ2x − Sˆ2y] terms in the spin Hamiltonian, and incorporating exchange interactions in a mean-field approximation. Fitted parameters are D/k=9.3± 0.5 K, E/k=−0.6±0.2 K, gx=2.23± 0.05, gy= 2.19 ± 0.05, gz=2.04 ± 0.05, and zJ/k=−0.235 ±0.02 K. At low temperatures the susceptibility exhibits a broad maximum with T(χmax)=3.23± 0.04 K and χmax =0.376±0.004 emu/mol. An antiferromagnetic transition at Tc=2.21±0.01 K is inferred from the position of a maximum in (∂χ/∂T), an ordering temperature in reasonable agreement with earlier Mössbauer results. The ratio Tc/T(χmax) =0.68±0.01 is suggestive of quasi-two-dimensionality. In the region of the maximum an acceptable fit according to a 2D- XY model with plausible parameter values can be achieved, but only with a ferromagnetic interlayer exchange interaction about 28% as strong as the leading antiferromagnetic intralayer interaction. Isotherms of M vs H show somewhat unusual curvature, the explanation of which is unclear.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.347792
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