ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Die entry pressures and elastic parameters derived from these have been determined for one low-density polyethylene (LDPE) at four temperatures using three dies having different entry angles. The elongational viscosity shows a somewhat different behavior with respect to temperature than the shear viscosity. Mostly the elastic parameters show a temperature-independent relation to the shear stress but only if the data at the lowest temperature used (130°C) are ignored. The latter data show that the material is much more elastic at this temperature than at higher ones; this is so even when the temperature is increased by only 20°C, after which any further increase gives negligible difference in elasticity. This behavior is probably due to a structural difference which may be a result of increased crosslink sites created by flow-induced crystallization. © 1995 John Wiley & Sons, Inc.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1995.070561107
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