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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1980 (1980), S. 693-698 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of Heteroaromatic Substituted Ureas and ChloroformamidinesCurtius degradation of heteroaromatic carbonyl azides leads to isocyanates, which react with amines to give the trisubstituted ureas 1. Some of these can be converted into the corresponding chloroformamidines 2 by chlorination with CCl4/(C6H5)3P.
    Notes: Der Curtius-Abbau heteroaromatischer Carbonsäureazide führt zu Isocyanaten, die mit sekundären Aminen zu den trisubstituierten Harnstoffen 1 reagieren. Einige dieser Harnstoffe können durch Chlorierung mit CCl4/(C6H5)3P in die entsprechenden Chlorformamidine 2 übergeführt werden.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1980 (1980), S. 699-702 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Heterocyclic Compounds from N-(2-Thienyl)chloroformamidines and N-NucleophilesN-(2-Thienyl)chloroformamidines 1a - c form unstable intermediates with nucleophilic reagents. These cyclize by two different mechanisms to give thieno[2,3-d]pyrimidines 2-5. Reactivities and mechanisms are discussed.
    Notes: N-(2-Thienyl)chlorformamidine 1a - c bilden mit geeigneten nucleophilen Reagenzien instabile Zwischenstufen, die nach zwei verschiedenen Mechanismen zu Thieno[2,3-d]pyrimidinen 2-5 cyclisieren. Reaktivitäten und Bildungsmechanismen werden diskutiert.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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