Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
86 (1987), S. 5989-5993
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The first example of transitions between almost free rotational levels of NH3 groups in the solid state is shown by the inelastic neutron scattering spectrum of Co(NH3)6(PF6)2, and can be interpreted in terms of a very weak sixfold potential. Additional satellite peaks are visible around the 0→1 rotational feature at high spectral resolution and it is shown that the temperature dependence of these satellites demonstrates that they originate from a coupling between NH3 rotors.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.452485
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