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Complex formation between 1,3,5-trinitrobenzene and 1,8-diazabicyclo-[5,4,0]-undec-7-ene (1988)

Collina, Gianni ; Forlani, Luciano

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 1 (1988), S. 351-357

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The title reaction is an instance of a simple nucleophilic attack of neutral nitrogen on aromatic sp2 carbon. The kinetic data (obtained in dimethyl sulphoxide) are compared to the results reported by the literature for the same reaction of aliphatic amines. Some possible interactions (substrate/nucleophile, substrate/salt) preceding the attack of the nucleophile are discussed.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610010605

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