ISSN:
1434-1948
Keywords:
Coordination modes
;
Cyclophanes
;
Macrocycles
;
Sandwich complexes
;
Solid-state structures
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A novel mode of containment for metal ions which participate in longer-range interactions with aryl rings (≥ 2.5 Å) is demonstrated in the preorganized cylindrical host 1. Three equatorial sulfur atoms in 1 hold metals in a trigonal planar ligand field between two apical benzene centroids at an M-Ar distance of about 3 Å. Evidence of an interaction between the π electrons and the metals is gained by 1H NMR spectroscopy of the complexes, and support for the general description of metal-arene contacts in the 2.5-3.5 Å range as ‘‘bonds’’ is derived from a statistical study of η6-coordination in the solid state. Crystal structures of [Ag(1)]BF4 and [Cu(1)]BF4 confirm the first examples of arene AgI and CuI sandwich complexation and indeed the only structurally characterized CuI-aryl centroid interaction. The two isomeric tris-sulfoxides derived from 1 show less tendency to interact with metals ions.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
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