ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The photooxidation of allyl chloride was studied by irradiation either in 100-L Teflon bags or in a 22.7-m3 Teflon smog chamber in the presence of added NOx. In the absence of added hydrocarbons, the reaction involves a Cl atom chain, which leads to a highly reactive system. A reaction mechanism is presented to account for the following photooxidation products: chloroacetaldehyde, formaldehyde, 1,3-dichloroacetone, 3-chloroacrolein, acrolein, glyoxal, chloroperoxyacetyl nitrate, and peroxypropenyl nitrate. The rate constant for OH reaction with allyl chloride at 298 K was measured by a relative rate method under conditions where the Cl atom chain length was small and was found to be kOH = 1.7 × 10-11 cm3 molecule-1 s-1. The rate constant for O3 reaction with allylchloride at 298 K was found to be kO3 = 1.5 × 10-18 cm3 molecule-1 s-1.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550180509
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