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  • 1
    Digitale Medien
    Digitale Medien
    Absolute quantum yield of O(1D2) in the photolysis of ozone in the hartley bandNRCC No. 17186. (1979)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 605-612 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The absolute quantum yield of O(1D2) in the photolysis of ozone in the Hartley band, between about 230 and 280 nm, has been determined using the isotopic exchange reaction between C16O2 and 18O(1D2). A value of 1.00 ± 0.05 has been obtained within a 95% confidence limit. A value of unity may therefore be accepted as the average quantum yield of O(1D2) atoms in the 230-280-nm region within an uncertainty of only several percent.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550110607
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Temperature dependence of rate constants for the reaction of atomic oxygen with hydrogen chlorideNRCC No. 19482. (1981)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 13 (1981), S. 945-956 
    Details
    ISSN: 0538-8066
    Schlagwort(e): Chemistry ; Physical Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A phase-shift method has been used to determine the rate constant for the reaction of ground state oxygen atoms with HCl over the temperature range of 330-600 K. Oxygen atoms were generated by modulated mercury photosensitized decomposition of N2O, and monitored by the chemiluminescence from their reaction with NO. After correction for diffusion of oxygen atoms from the viewing zone, the rate constants can be represented by the Arrhenius equation k1 = (3.06 ± 1.43) × 1012 exp[(-3160 ± 184)/T] cm3/mol·s. The indicated uncertainties are 95% confidence limits for 15 degrees of freedom. Also, the third-body efficiency of HCl relative to N2O in the reaction O + NO + M ← NO2 + M was determined to be 1.9 ± 0.2 over the temperature range of 298-360 K.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/kin.550130916
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