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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 5019-5027 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The validity of the adiabatic approximation applied to systems of two coupled oscillators–typically represented by the Henon–Heiles' Hamiltonian–is examined. Through explicit analytical estimates of nonadiabatic couplings, it is shown that the adiabatic approximation is appropriate in all cases, except for the case of 1:1 Fermi resonance between the two oscillators. In this case, nonadiabatic couplings are found to be important already at an excitation energy of about two quanta, i.e., at much lower energies than Ec, the critical energy for the classically observed quasiperiodic–chaotic transition. Nonadiabatic interactions are dominantly horizontal at these energies (E〈Ec), however, indicating some regularity in the energy spectrum at low excitation, despite the early breakdown of the adiabatic separation.
    Type of Medium: Electronic Resource
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