ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
A deuterium isotope effect on the arene-alkene meta photocycloaddition, reported earlier for toluene/toluene-d8 photoaddition to cyclopentene, was found to depend on the concentration of both arene and alkene. This phenomenon is explained in terms of an unbalanced dissociation of ‘mixed’ excimers, which play a role in the intermolecular competition experiments.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610030411
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