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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 2015-2018 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We present a very efficient 90° sector magnet mass spectrometer detector, based on electron impact ionization, especially adapted for the use with atomic and molecular beams. In this setup, a cylindrically symmetric magnetic field compresses electrons emitted from a large filament into a long, narrow volume containing primarily the molecular beam. This has the advantage of both producing as little as possible background from residual gases and increasing the interaction region between beam and ionizer. Experimental tests using thermal He atoms show that the detector's efficiency and sensitivity are very high, amounting to η≥0.70±0.04% and S=0.22±0.03 A mbar−1, respectively. The unconventionally long ionization volume, however, may restrict the use of this mass spectrometer to experiments with no, or only moderate timing requirements. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: 36.40.01 ; 33.80.Gj
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Optimized geometries and binding energies are calculated for ethene (ethylene) dimers, trimers, and tetramers based on a pairwise additive dimer potential. From these results intermolecular frequencies and relative abundancies (catchment areas) of the different isomers are obtained and compared with the results of accurate measurements of the photodissociation upon absorption of one photon of a CO2 laser in the region of thev 7 monomer absorption band at 949 cm−1. The clusters are size selected in a scattering experiment and show for a cluster size fromn=2 ton=6 a frequency maximum shifted by 3 cm−1 to the blue compared with the monomer. The result is explained by the predominance of chains and chain-like structures of the clusters in the photodissociation process. The chains consist of cross-like dimer sub-units.
    Type of Medium: Electronic Resource
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