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Synthesis of rac-(E)-Opposita-4(15),7(11)-dien-12-al (1999)

Weyerstahl, Peter ; Marschall, Helga ; Degenkolb, Peter ; [weitere]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 675-678

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Details

ISSN: 1434-193X

Schlagwort(e): rac-(E)-Opposita-4(15),7(11)-dien-12-al ; Natural products ; Vetiver oil ; Octahydroindene derivatives ; Fragrances ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: -rac-(E)-Opposita-4(15),7(11)-dien-12-al (1) was synthesized in 12 steps via the aldehyde 11 as the key compound. The spectroscopic data of rac-1 are identical with those of the corresponding natural product, previously isolated from Vetiver oil. Synthetic rac-1 has a strong, green woody odor with soft-floral undertones, which confirms that 1 is an olfactorily important constituent of Vetiver oil.

Zusätzliches Material: 1 Tab.

Materialart: Digitale Medien

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