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A test of the concept of ‘charge localisation’ in methionine (1975)

Den Heuvel, C. G. Van ; Nibbering, N. M. M.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 10 (1975), S. 250-258

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A previous re-investigation of methionine has shown that the [C2H5S]+ ion is generated via rather complicated routes from the molecular ion. This has been interpreted as evidence against charge localisation in the fragmentation of the title compound. Deuterium labelling, high resolution mass measurements and metastable transitions have revealed, however, that the formation of the [C2H5S]+ ion is not in contradiction with the predicting capabilities of the concept of charge localisation.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210100403

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