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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 704-706 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: New data on a highly reliable interconnect material based on aluminum will be presented. As compared with conventional Al-Si-Cu alloy films, quaternary Al-Si-V-Pd films with only 0.1 at. % vanadium and 0.1 at. % palladium combine excellent plasma etchability with good corrosion resistance. Electromigration tests of Al-Si-V-Pd films have shown a surprisingly high stability at 180 °C. Studies of microstructural attributes show: (a) for Al-Si-V-Pd relative to Al-Si, texture is not significantly changed and average grain size is slightly increased, and (b) the dominant factor leading to a highly stable microstructure is the combined presence of finely dispersed, small precipitates of both (Al,V) and (Al,Pd) phases.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 988-995 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Tungsten thin films were deposited on glass substrates by direct-current planar magnetron sputtering. The induced thickness-averaged film stress within the plane of the film was determined with the bending-beam technique and changed from compressive to tensile on increasing working-gas pressure. The microstructure of these films was investigated by cross-sectional transmission electron microscopy. Compressively stressed films consisted of tightly packed columnar grains, whereas in films with a maximum value for the tensile stress the onset of a void network surrounding the columnar grains was observed. High-pressure conditions resulted in dendritic-like film growth, which brought about complete relaxation of internal stresses. The α phase was predominantly found in films under compression, while an increasing amount of β-W coincided with the transition to the tensile stress regime. Special attention was focused on stress-depth dependence and the development of two overlapping line profiles in x-ray diffraction (XRD) diagrams with film thickness as observed in compressively stressed films. Both findings constitute a remarkable result in respect of stress-depth distributions in thin films: the presence of two sublayers in a monophase film, one experiencing tensile and the other compressive stress. The occurrence of a modest tensile stress maximum present in the substrate-adjacent part of the film was explained by an elastically accommodated volume reduction, associated with a phase transformation (β into α) of initially formed β-W. Furthermore, a comparison of bending-beam stresses and XRD lattice strains (utilizing the sin2 ψ method) provided a consistent view of the mechanical behavior of the differently strained sublayers in this monophase (α-W) film.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3003-3010 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Significant large-scale modification of the surface of Al–Si conductors was observed, due to electromigration in wide lines and under low stress conditions. After electromigration stressing the Al layers showed local thickness variations, i.e., damage by thinning. The mechanism underlying this damage causes substantial metal transport. Nevertheless, damage by thinning has received little attention in the past. Thinning was observed: (1) in a number of different alloys (Al–Si, Al–Cu, Al–Si–V, and Al–Si–V–Pd), (2) with a number of different underlayers [SiO2, W–Ti (no vacuum break after Al deposition) and W–Ti (oxidized surface before Al deposition)], (3) over an extended temperature range, (4) over a range of current density, and (5) in structures with and without passivation. The results show that thinning is a general phenomenon. An activation energy of approximately 0.5 eV was determined for the temperature dependence of a combined mechanism of concurrent thinning plus voiding in Al99Si1. Several alternatives are examined to explain the observations, namely mass movement along dislocations, Al bulk diffusion, and diffusion at the interface between the Al and its oxide. It is shown that diffusion at the Al/Al oxide interface most probably plays an important role in the damage mechanism, even under stress conditions where grain boundary diffusion is traditionally thought to dominate. Results also showed that alloying of Al with Pd can reduce the effects of damage by thinning. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 571-577 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A comparison has been made between the Al via fill mechanisms in both reflow and forcefill processes. Cross-sectional transmission electron microscopy has been used to study the Al transport into the vias as a function of time. Our analysis shows that reflow and forcefill results can be explained by a stress relaxation model. We propose that the transport of aluminum into the vias as a function of time is described by both diffusion and dislocation movement. In the case of reflow at high temperature, the vias may be filled completely, after closure, by high-temperature creep of Al. In the case of forcefill, an additional high stress has been applied which raises the strain levels such to activate the dislocation glide and climb mechanism. The results from detailed investigations of the microstructure by cross-sectional transmission electron microscopy support these new insights. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 4301-4308 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Mo thin films were deposited on glass substrates using direct-current (dc) planar magnetron sputtering. Mechanical determination of the internal stresses, using the bending-beam technique, yielded typical compressive-to-tensile stress transition curves with increasing working-gas pressure. The microstructure of the compressively stressed films consists of tightly packed columns, whereas in the tensily stressed films the development of a void network structure surrounding the columnar grains is observed. At elevated working-gas pressures the onset of microcolumns is observed in the initial stage of film growth. Determination of lattice strains by x-ray diffraction (XRD), utilizing the sin2 ψ method, encounters more difficulties than the more straightforward stress determination by the bending-beam method. Here special attention is focused on deviations from linear dependence of dψ with sin2 ψ along with asymmetry of XRD line profiles that results from stress-depth profiles as well as lateral stress distributions in the tensily stressed films. These anomalies and the discrepancy between bending-beam stresses and XRD lattice strains, observed for high working-gas pressures, can be interpreted in terms of microstructural features revealed by cross-sectional transmission electron microscopy.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 889-891 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Boron marker-layer structures have been used to analyze the heating ramp-rate dependence of transient enhanced dopant diffusion (TED) during rapid thermal annealing of Si implantation damage. The study uses short anneals with heating ramp rates in the range 0.1–350 °C/s, and peak temperatures in the range 900–1100 °C. Increasing the ramp rate is found to reduce the amount of profile broadening caused by TED, as well as reducing the smaller amount of normal "thermal-equilibrium" diffusion which is related to thermal budget. The results show why high ramp rates lead to improved B-implant activation and junction-depth control in Si devices. An Ostwald ripening model of interstitial-cluster evolution describes the detailed trends in the data and predicts further improvements in the case of ultrarapid annealing. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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