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  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental program was conducted to study the thermochemical, flammability and toxicological characteristics of uncoated and coated polyisocyanurate foams. The coatings used were fluorinated copolymer and an intumescent material. Flammability testing methods included the XP-2 chamber smoke test, ASTM D-1692, infrared photography, Bureau of Mines penetration test, and a JP-4 fuel combustion chamber. The results of these tests are presented in a companion paper. Combustion and pyrolysis gases were analyzed by gas chromatography and mass spectrometry. The LD-50 and LD-100 tests were performed on Sprague-Dawley rats housed in an environmental chamber. The isocyanurate foam, flourinated-copolymer-coated foam, and the intumescent-coated foam were found to have excellent flammability and insulation characteristics, although smoke development was substantial. The LD-50 values for Sprague-Dawley rats, based on a two-week survival, were approximately 2.0 gm/ft3 for all three materials. Examination indicated an absence of any significant cause of death except carbon monoxide poisoning.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 167-178 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental program was conducted to study the thermochemical and flammability characteristics of an improved polyisocyanurate foam, uncoated and coated either with fluorinated copolymer or an intumescent material. Testing methods included thermal analysis; scanning electron microscopy; infrared photography; infrared spectroscopy; HLT-15, ASTM D-1692, Bureau of Mines Penetration, and XP-2 smoke chamber flammability tests; limiting oxygen index (LOI); and a moderate-scale fire simulation test. The uncoated and coated foams were found to have excellent flammability and insulation characteristics, although smoke development was substantial.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The response of a HDPE, a L-LDPE and a PP homopolymer to processing conditions and processing stabilizer formulations in the 220°C to 280°C temperature range was investigated. The technique of multiple extrusion was used. Melt flow and melt flow ratio were measured after the first, third and fifth extrusion pass. In the case of the HDPE and the L-LDPE, degradation by cross-linking was the predominant reaction and the molecular weight distribution showed a significant broadening compared to the virgin samples. The PP homopolymer degraded by chain scission. By adding a multifunctional hindered phenol and a hydrolysis resistant phosphite, all polymers could be efficiently protected against degradation on processing. For the HDPE and the L-LDPE, increased amounts of phosphite provided increased processing stability at constant phenol concentration. A 4:1 ratio of phosphite to phenol exhibited the best performance. The most efficient ratio for protecting melt flow of the PP homopolymer was found when a two to one ratio of phosphite to phenol was added.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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