ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Stress-strain and stress-relaxation behavior of polyurethane elastomers based on poly(ethylene adipate), poly(ethylene maleate), polyethylene glycol, and 4,4′-diphenylmethane diisocyanate (MDI) have been studied. The elastomers were crosslinked by an excess of MDI and by dicumyl peroxide (DiCup); the latter was supposed to form additional crosslinks on the unsaturated bonds. The determined values of Young's modulus, Mooney-Rivlin elastic parameters C1 and C2, relaxation moduli E(10 sec) and E(100 sec), as well as relaxation speed were used to estimate the effect of MDI- and DiCup-formed crosslinks on the mechanical behavior of polyurethanes. It was found that while the elastomers crosslinked by MDI only apparently displayed viscoelastic properties, the polyurethanes additionally crosslinked by DiCup exhibited more elastic behavior. The results obtained were explained on the basis of changes in the amount of secondary bonding due to the additional network junctions formed by DiCup at nonpolar groups.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1978.070220514
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