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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 113 (2000), S. 10367-10376 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A method is presented for modeling the geometrical packing of polydisperse mixtures of both spherical and nonspherical particles, which are models for filler particles used in the manufacture of polymer composites. The technique is based on the calculation of the dissipative dynamics of an ensemble of fused soft spheres at constant temperature and pressure. After validation of the method at low pressures by comparison with analytical equations of state for monodisperse and binary mixtures of hard spheres, the random packing of fused soft sphere cubes was studied. The effect of packing cubes together with spheres of varying size was then examined, with the aim of developing an understanding of how to minimize the amount of void space in composites containing angular particles. In one case, entropically driven demixing was observed in a cube-sphere mixture. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 5667-5676 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Absolute rate theory and the sticking probability approach have been previously examined as possible means of predicting the rate of adsorption. However, when applied to examine adsorption kinetics, they have been found not to contain the coverage and pressure dependence required for several important systems including CO–Ni(111). Statistical rate theory (SRT) is being developed with the objective of predicting the rate of molecular (or atomic) transport across the interface between macroscopic phases in terms of experimentally controllable variables and material properties of the two phases. Previous applications of SRT to adsorption have been limited to systems for which both the gas phase pressure and the temperature could be assumed to be constant. Herein, the SRT approach is extended to systems in which the number of molecules in the system (and hence the gas phase pressure) is not constant. To examine this extension, SRT is used to formulate the equations governing the rate of adsorption in isothermal, beam-dosing experiments. These equations are then combined with the values of certain material properties that have previously been established and a hypothesis that the value of the equilibrium adsorption cross section is given by the area of an adsorption site. The kinetic data for CO adsorbing on Ni(111) data reported by three different laboratories are then examined. For each set of experimental data, constants had to be inferred that were related to the experimental apparatus used and as such they were not expected to have any coverage or pressure dependence. The good agreement found between the predicted and measured adsorption kinetics indicates that all of the necessary coverage and pressure dependence was explicitly predicted from the SRT approach. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 5677-5684 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The equation traditionally used to interpret temperature programmed desorption (TPD) spectra, the Polanyi–Wigner equation, does not contain explicitly the coverage and temperature dependence necessary to predict TPD spectra in several important systems including CO–Ni(111). Herein, the statistical rate theory (SRT) approach is used to formulate equations for temperature programmed desorption which are then used to examine TPD spectra reported in the literature for CO–Ni(111). The molecular and material properties for the CO–Ni(111) system have been previously established. One experimental spectrum has been chosen to determine the apparatus constants. The material properties and the apparatus constants are then used in the SRT equations to predict the eight additional TPD spectra for different initial coverages. A critical comparison can then be made between the theory and these eight experimental spectra, since no fitting constants were used in these eight cases. The results show that there is clearly qualitative agreement. The SRT equations are then used along with the heat of adsorption to derive an equation for the pre-exponential factor appearing in the Polanyi–Wigner equation. A prediction is made for the pre-exponential factor that is in agreement with that found empirically. The agreement found between the SRT predictions and the measured spectra indicates that all of the coverage and temperature dependence necessary to predict TPD spectra is given explicitly by the SRT approach. Hence, the experimental support for the SRT approach is enhanced. The SRT equations are then used to predict CO–Ni(111) spectra that would occur if the heating rate were varied. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford UK : Blackwell Science Ltd
    Freshwater biology 46 (2001), S. 0 
    ISSN: 1365-2427
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: 1. Connell’s (1978) intermediate disturbance hypothesis (IDH) has been proposed as one explanation of why diversity is often highest at intermediate levels of disturbance. We used a model phytoplankton responses to environmental change (PROTECH) to investigate the validity of this hypothesis.2. In a simulated phytoplankton assemblage of eight species, we found that the relationship between the increased intensity of a single forcing event and diversity was described by a positively skewed curve.3. A progressive increase in forcing frequency introduced a sharp decrease in diversity at a threshold frequency. However, the highest diversity values were found at an intermediate frequency of disturbance.4. We described the shape of this breakpoint response as like a ‘cliff’ and reconcile it with multiple stable-point theory. It is argued that the IDH should possibly be represented by this ‘cliff’ relationship, which may be applied to (or encourage the re-examination of) many previous studies.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1365-2427
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: 1. A phytoplankton community model [Phytoplankton RespOnses To Environmental CHange (PROTECH)] was used to examine the effect of a wide range of varied light intensities and mixed depths upon simulated phytoplankton populations. Two different column lengths of the simulated water body were examined (the upper 5 m and the whole 14.5 m water column) for each scenario.2. The hypotheses tested were that: (i) under low light intensity and/or deep mixing the simulated community will be dominated by a phytoplankter with a low critical light intensity; (ii) at high light intensity and shallow mixing the simulated community will be dominated by small, fast-growing phytoplankters; (iii) under all conditions, except deep mixing, the largest proportion of phytoplankton biomass will be found near the surface.3. It was found under most conditions that, although there was a bloom in the upper column (dominated by algae such as Chlorella, Ceratium or Rhodomonas), the largest phytoplankton biomass in the water column was located 9 m below the surface and consisted of solely Asterionella. This bloom was missed by the 5-m samples. Thus, using the whole column sample lengths, hypothesis (i) was not rejected but hypotheses (ii) and (iii) were refuted.4. The inclusion of specific movement characteristics of phytoplankton in the model allowed the possibility of the dominance of multiple spaces within the water column and should be included in any model-based investigation of this topic. Further, the results from the model suggest that a reduced depth of mixing creates greater environmental heterogeneity, allowing more species to persist.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Clinical & experimental allergy 8 (1978), S. 0 
    ISSN: 1365-2222
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Ground whole rye and airborne rye dust of comparable size distribution were tested for their ability to activate the complement cascade via the alternative pathway. Precipitin-negative pooled normal human serum was incubated with increasing amounts of the two rye dusts. Electrophoresis of the resultant supernatant fluids demonstrated the conversion of the proactivator of the third component of complement to the gamma-migrating activator of the third component. This activation was completely prevented by pre-treating the serum with the chelator EDTA, while pre-treatment with EGTA allowed suboptimal arc conversion, strongly implying that complement was activated via the alternative pathway. Quantification of the supernatant fluids showed dose-dependent complement consumption as defined by both CH100 immunoditfusion and CH50 tube haemolytic techniques.Airborne rye dust showed a greater quantitative potential than ground whole rye for activating the alternative pathway. These results indicate the possibility of the direct action of airborne organic dusts on the induction of inflammatory sequelae in the lungs of both sensitized and unsensitized individuals.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1600-0633
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: From July 1989 to December 1994, an echo sounder provided monthly estimates, usually for both day and night, of pelagic salmonid densities in the North and South Basins of Windermere, the largest natural lake in England. Sampling was along contiguous transects, three in the North Basin and five in the South Basin. Records for Arctic charr (Salvelinus alpinus) could not be separated from those for brown trout (Salmo trutta), but previous sampling by gill-nets and anglers showed that charr formed over 90% of this mixed population in the North Basin and about 60–75% in the South Basin. Associated with the increasing eutrophication of the lake, there has been a decline in anglers' catches of charr and, since 1984, an increase in brown trout taken in the pelagic zone of the South Basin. The echo-sounder data showed that pelagic salmonid density in the North Basin was about two to five times that in the more eutrophic South Basin in 1989, 1990 and 1991. Since the start, in April 1992, of the reduction of phosphorus discharged from sewage works, this ratio has decreased, especially at night when the highest densities were recorded. This improvement was chiefly due to a significant (P〈0.001) increase in the density of small fish (length 〈20 cm), in both the upper (depth 〈20 m) and deeper (depth 〉20 m) water layers. Although a similar improvement has still to be shown in the upper water layer by larger fish above the size limit for removal by angling (20 cm), there has been a significant increase (P〈0.01) in the density of these fish in the deeper water layer of the South Basin. The increased density of small fish suggests that the stock available to charr anglers (fish 〉20 cm at water depths 〈20 m) should increase in the next few years, especially in the South Basin. It is therefore important to continue the monitoring program and thus ensure that there is advance warning of any marked changes in charr stocks.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of fish biology 47 (1995), S. 0 
    ISSN: 1095-8649
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: The critical thermal maximum for salmon and trout parr was not affected significantly by age or acclimation temperature, and increased asymptotically with the rate of temperature increase. Mean thermal maxima were estimated with poor precision at high and low rates of temperature increase, and high precision at rates of 1 and 2°Ch−1.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 25 (1969), S. 2420-2420 
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 32 (1999), S. 1069-1083 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A model-independent maximum-entropy method is presented which will produce a structural model from small-angle X-ray diffraction data of disordered systems using no other prior information. In this respect, it differs from conventional maximum-entropy methods which assume the form of scattering entities a priori. The method is demonstrated using a number of different simulated diffraction patterns, and applied to real data obtained from perfluorinated ionomer membranes, in particular Nafion™, and a liquid crystalline copolymer of 1,4-oxybenzoate and 2,6-oxynaphthoate (B–N).
    Type of Medium: Electronic Resource
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