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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 463-472 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of synthesizing reactive mass-exchange networks (REAMENs) is addressed for which the equilibrium relations governing the transfer of a certain species from rich streams to reactive mass-separating agents are nonlinear (convex and/or nonconvex). Previously developed synthesis procedures for REAMENs are not applicable to such cases, since they were developed for cases of linear and/or convex equilibria. Two peculiar phenomena are associated with REAMENs with general nonlinear equilibria: the location of a mass-exchangers may straddle the pinch point even for networks featuring the minimum cost of mass-separating agents. To account for such intriguing characteristics, a systematic procedure is developed to synthesize cost-effective REAMENs with general nonlinear equilibria. In addition, a robust solution procedure is devised to guarantee the identification of the global solution of the developed optimization programs. Applicability and usefulness of the proposed synthesis procedure are demonstrated via a case study on the desulfurization of gaseous wastes from a coal-to-methanol plant.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3087-3101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article introduces the novel concept of synthesizing waste-interception networks (WINs) and incorporates it within a mass-integration framework for the global allocation of pollutants. The essence of this notion is to provide selective interception and rerouting of undersirable species at the heart of the process instead of dealing with the pollutants in the terminal waste streams. It also provides a unified framework for simultaneously tackling gaseous and liquid pollution. Several tools are developed to track the pollutant throughout the process and determine the optimal interception policies. The problem is formulated as an optimization program that seeks to determine the optimum locations for intercepting the pollutants, extent of separation, and separating agents to carry out the interception tasks. Furthermore, the WINs can be used within a mass-integration scheme for the global allocation of species throughout the plant. These new concepts and associated mathematical formulation are demonstrated using a case study on the removal of a chlorinated hydrocarbon. This approach has benefits over conventional recycle/reuse (such as MEN synthesis).
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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